Beyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry
نویسندگان
چکیده
منابع مشابه
The Fascination of Polyoxometalate Chemistry
We are delighted to introduce this special issue of Inorganics. This themed issue is dedicated to polyoxometalates (POMs) as an outstanding class of oxo-cluster materials. Polyoxometalates have fascinated generations of researchers since the mid-18th-century, and they continue to attract promising young scientists all over the world. Since the first pioneering studies, the manifold structures a...
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Grafting of C-6, C-16 and C-18 alkyl chains onto the hydrophilic Mn-Anderson clusters (compounds 2-4) has been achieved. Exchange of the tetrabutyl ammonium (TBA) with dimethyldioctadecyl ammonium (DMDOA) results in the formation of new polyoxometalate (POM) assemblies (compounds 5-6), in which the POM cores are covalently functionalized by hydrophilic alkyl-chains and enclosed by surfactant of...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2019
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201905600